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For nano-grinding in a ball mill, the grinding jar and balls have to be of a very abrasion-resistant material, such as zirconium oxide, to minimize contamination of the sample material by abrasion. Factors like the choice of dispersion medium or grinding ball size .

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A ball mill is a type of grinder used to grind and blend materials for use in mineral dressing processes, paints, pyrotechnics, ceramics and selective laser sintering. It works on the principle of impact and attrition: size reduction is done by impact as the balls drop from near the top of the shell.

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Medium diameter used for nano-grinding is necessarily small in order to increase the number of impacts and the surface area for impact in the mill. Most of the surface area in the mill is thus the media surface area, A media ; the mill surface area, A mill, makes a small contribution as is shown below.

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In particular, mechanical attributed contamination by the milling tools (Fe or WC) as well as ambient gas (trace impurities such as O 2, N 2 in rare gases) can be problems for high-energy ball milling. However, using optimized milling speed and milling time may effectively reduce the contamination.

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